.5B.28dppf.29Ni.28cinnamyl.29Cl.29.5D Nickel(II) precatalysts

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structure of dppf



synthesis of [(dppf)ni(cinnamyl)cl)]



the authors investigated reduction of [(dppf)ni(cinnamyl)cl)] , found [(dppf)2ni(0)] formed quantitatively in 10 minutes @ room temperature upon addition of 2-thienyl boronic acid , k3po4.



reduction of [(dppf)ni(cinnamyl)cl)] ni(0)









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